Thursday, Jan 23, 2003 at 17:13
Actually, not so.
If the fully charged battery has a voltage of, say, 12.7v at no load, there will be an initial current flow and the voltage of both will rapidly settle at a voltage
well above 12v. The current flow is
well within safety limits for the batteries. The characteristic of lead acid batteries is that little charging occurs below about 13.0v, so after the initial current there will be not much change in the amount of charge in either, and little current flow.
For example. It takes 45 hours to recharge a 100% discharged battery to 90% charge at a voltage of 13.0v. (from a reference I have) So if the voltage is 12.3v the time would be essentially infinite because the voltage is way below that at which the battery accepts significant charge.
So what you get is an almost fully charged battery and a slightly charged one even though they are connected together. Only a charging voltage above about 13v will equalise the charges because the flat battery will accept current and the full battery little.
As an aside,
When the NRMA jump starts a vehicle with a flat battery using one of those portable battery packs there is no great spark when it is connected.
There are some good references to the characteristics of lead acid batteries on the web and these have been quoted in this
forum recentlly Unfortunately I have not got them to hand right now.
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