Sunday, Aug 19, 2012 at 15:25
Hi Phil,
The chemistry behind a lead acid battery is pretty straighfoward, but as anyone who has ever posted in electrical threads knows, there is always controversy!
I did preface my answers by stating it would take an essay to explain and so have tried to simplify my answers. Most people are familair with low reistance equals high current flow. So, simplisiticallly, as a flat battery draws a high current, its resistance would appear to be low. Conversely, a fully charged battery draws very little current hence it appears to have a high internal resistance.
The reality is that in a flat battery, virtually all the sulfuric acid has been converted to water, the chemical reaction (simplistically!) is that the sulfate has reacted with the lead to form lead sulphate. Now water has a much higher resistance than sulfuric acid so the actual electrolyte resistance of a flat battery is high!
However, if one applies a fixed voltage source to a battery, the flat battery will draw more current than a fully charged battery. The difference is the state of charge and its effect due chemical reaction that is occuring (the lead sulphate is changing back to lead oxide and lead). A battery has ohmic, inductive and capacitive resistance and to look at the ohmic reistance only takes away from the point I was trying to make.
One can discuss all day techincal detail about a battery, but the point I was trying to make is that a flat battery can accept more current than a charged battery for a given voltage.
Hi Brodie,
I too have AGM batteries in my Camper and I fully recharge them when I get
home and once charged, I only put them back on charge periodically.
While my Ctec 25A charger is a multistage one, I have seen its float voltage creep too high for my liking (gets above 14V, should be closer to 13V) so once fully charged I turn it off. About every 2 weeks I put the charger back on to top up the batteries, as all batteries have some level of self-discharge.
Some people will leave the charger on all the time and that is fine, provided the float voltage is OK. But fully charging the battery but then leaving the charger off for extended time is not what I would do.
Cheers
Captain
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