Monday, Jan 11, 2016 at 01:04
Sorry, Bantam - You're the one full of crap. I've owned 100's of items of equipment and fleets of vehicles over more than 50 yrs, to have enough hands-on experience that showed me, that there's that many variations in ready-mixed coolant and coolant additives - that these variation makes a major difference in corrosion protection performance.
In fact, when I started in business, about the only coolant additive available, was soluble oil!
The basic ingredient of manufacturers coolant and antifreeze, produced since before WW2 is Ethylene Glycol.
However, manufacturers add their own mix of additional additive chemicals to EG, that are tailored to the metals mix in their engines.
There are up to 7 or 8 additional chemicals added to EG to inhibit corrosion and to provide anti-freeze abilities.
Some of these chemicals are - Nitrites, Silicates, Phosphates, Chromate, Tolyltriazole and Mercaptobenzothiazole - and Organic Acids. There are more - these are just off the top of my head.
The green/yellow coolants contains largely silicates and phosphates as corrosion inhibitors - the orange/pink/red coolants contain complex organic acids as corrosion inhibitors.
The colours are added via dyes, for coolant group compatibility identification.
These two colour groups are not compatible, because the organic acids used in the orange/pink/red coolants react chemically with the silicates and phosphates in the green/yellow coolants, to create new chemical compounds, that degrade the coolants ability to protect against corrosion.
Mixing these two different coolant groups can cause coolant gelling, and even accelerated corrosion.
Nearly all engines used to be fully cast iron - today we have engines that are a mix of aluminium and magnesium alloys, combinations of cast iron and alloys - and we have wide variations in the mixtures of metals added to aluminium alloys.
We have aluminium alloys used in heads and blocks today, that contain nickel, or iron, or silicon, or all three, in the aluminium alloys.
We used to have brass and copper radiators - nowadays, nearly all radiators are aluminium or aluminium alloy.
Cummins engines are notorious for cylinder liner electrolysis, caused by liner vibration. If you use off-the-shelf el-cheapo ready-mixed coolant, or corrosion inhibitors, in your Cummins engines, you can expect holes in your liners long before your engine wears out - thus destroying your engine.
Use the OEM Cummins coolant, and you'll find the coolant is tailored with the correct chemical additives (higher levels of nitrites) to combat the liner electrolysis, by coating the liners with a layer of nitrite, that inhibits electrolysis.
I've bought basic, off-the-shelf el-cheapo plain green ethylene glycol, and used it in early Holden V8's - and had the alloy inlet manifolds corrode out within 2 yrs.
I changed to the genuine Holden coolant with the necessary chemical additives for the alloy in Holden engines, and the corrosion problem vanished.
Even Holden had some serious problems with their recommended coolant in early Commodore V6's.
The Commodores had serious cooling system corrosion problems, and Holden had to change their coolant package to defeat the corrosion problem the Commodore V6's had.
The chemical additive mix in coolants is a finely-balanced act - sort of like cooking a perfect cake.
Get the recipe wrong, and you have a disaster on your hands.
I know enough about chemicals to understand complex chemical reactions, and how finely balanced many chemical compounds are - and how quickly chemical compounds and additives can react or break down.
I've owned my own lab for chemical/metals testing, complete with an Atomic Adsorption Spectrometer - and I know how to use an AAS.
Add more chemical compounds to other chemical compounds, without knowing the full and precise chemical makeup of each, and you can create some serious chemical reactions, that produce adverse results.
Controlling corrosion and electrolysis in various engines and cooling systems with the vast array of current modern metals in those systems, is a black art - but the start of that black art, is to use the manufacturers tailored coolant - which is designed in its chemical additive makeup - by the manufacturers engineers - to protect the precise metals and combinations of alloys, used in their engines.
It's that simple. Use an off-the-shelf el-cheapo plain ethylene glycol from some place like Repco or Supercheap, and you're asking for corrosion problems, if you have a current model vehicle, with a mix of alloys in the cooling system.
Below is an interesting SAE write up, about Ford going to one world-wide coolant for all their engines.
However, to move to that one world-wide coolant, Ford have had to do a lot of engine modifications and checks on compatibilities, before they make the move.
SAE - Article 8242 - Ford moves to one type of engine coolant, worldwide
Cheers, Ron.
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