Thursday, Mar 04, 2010 at 21:15
John,
My background is 40 years as a Research Chemist in the oil industry.
Some of the comments above are not well informed including those from people claimining some association with the Refining of crude.
The issue you mention concerning leaking seals after the introduction of Low Sulphur distillate was caused by the Refining process removing an increased proportion of Naphthenic and Aromatic components from the end product along with the sulphur.
The lower level of these Aromatics/Naphthenics reminining in the fuel allowed the seals to shrink reducing the interference fit thus allowing leakage.
The oil companies responded by adding seal swell additive to the fuel.
The Sulphurised terpenes and naphthenes that were removed during the desulphurising process were in fact the significant antiwear compounds in the higher sulphur fuel of past years. These compounds decomposed at the interfeace of metal to metal contact in the pump surfaces creating active sulphur compounds that bound to the metal {Iron} surface creating a sacrificial Iron Sulphide type layer that was worn away preferentially therby reducing the amount of metal removed during operation.
As an example the same process is at work in differential oils interaction with the gear teeth.
Two stroke oil particularly low ash Marine two stroke [TCW 3 spec] has some very good active antiwear compounds, not quite of the calibre of the Sulphurised compounds in fuel and gear oil but nonetheless they do reduce the wear rate in the pump.
The best products to use are specially formulated for the reduction of extreme pressure wear as in fuel pumps. Products like Opti-Lube and Flashlube are typical.
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