Sunday, Oct 02, 2011 at 11:44
Thanks Phil for the Google reference. That took me to the Tvan
forum where you have also reported the problem. A contributor there stated: “Common in any current carrying untinned copper wire exposed to moisture. For some reason black insulated wires or negative wires seem more prone.
When you replace it make sure you prevent moisture ingress into the cable. This can be done by using dielectric grease and sealing the cable end connection with heat shrink, or alternatively using glue lined heatshrink, available at Jaycar.”
The problem seems very common in radio controlled model planes (affects NiCd battery packs) and on reflection, in much earlier model railway days, I had seen it on 12v wires in that field as
well and can recall the difficulty in soldering affected wire.
Another Google reference stated: “The condition almost always occurs on the negative leads, although it can occur on the positive leads as
well. Black-Wire Disease occurs when the electrolyte (concentrated potassium hydroxide paste) leaks from the NiCd via the vent or seals, and comes in contact with the wire. Once copper oxide is formed, it acts as a wick, gradually drawing more potassium hydroxide along the wire, further and further from the pack. This wicking action can be very destructive, and Black-Wire can and will pass through switches, and continue to spread throughout …. the circuitry.
This is very interesting & a potential problem we should be on the
lookout for, particularly where there is an obvious loss of power between battery and van/car appliances. The jury seems to be still out on whether it is caused by a leakage of battery fluid into the negative wire, whether it is a
breakdown of the untinned wire, maybe through moisture penetration and oxidisation or both! Obviously, one solution to the problem is the use of quality tinned wire when vehicles are being manufactured but that is unlikely to happen any time soon as manufacturers struggle to remain price competitive and in most cases, the problem does not occur until
well outside of the warranty period.
Lesson: consider black wire disease as a potential cause of loss of power in all situations.
Camperman2
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