Friday, Jan 06, 2012 at 13:36
Hi OldBob,
presuming the OP has AGM batteries which are superior in many ways to wet cell starting batteries, when used in a solar application, the expected ocv is higher for reasons given below.
But yes, in case the OP does use wet cell starting batteries for his solar gear, then you're right, a modern Ca/Ca battery has an ocv of ~12.8V, and older technology Sb/Sb is closer to 12.6V.
Asian sourced AGM batteries have slightly stronger electrolyte.
They do this to bump up the ionic conductivity for high charge acceptance and high discharge capability.
Another welcome side effect of higher electrolyte concentration is improved battery efficiency which can be 3~4 times higher than that of a typical flooded cell starting battery. This comes in handy when storing
solar power with gains of 10% and higher compared to flooded cell.
The drawback of stronger electrolyte is of course higher rate of
grid corrosion especially under high operating temperatures (e.g. when mounted under the bonnet).
cheers, Peter
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