Sunday, Jan 22, 2012 at 18:20
Hi Peter,
thanks for pointing this out, but I wasn't actually implying 'back flow' of current from the battery to the charger.
The reason why, at 13.2V float, the negative electrodes inside the AGM battery slowly discharge, has got something to do with the gas recombination cycle.
In a nutshell, oxygen gas formed on the positive plate during charging, diffuses to the negative plate where it effectively reduces the polarisation of the electrode. If the recombination cycle becomes too efficient (like in a partially dried out cell), or the over potential of the cell isn't kept high enough, the negative electrode's polarisation can go to zero, or even negative.
Once it's in the negative region, the negative electrode is being discharged by a portion of the small float charging current.
The cell voltage thresholds below which this can happen are in the vicinity of 2.25V for fresh AGM cells, and 2.31V for aged ones.
So one would have to be brain dead, to suggest a float charging voltage of only 2.2V per cell, like this particular charger manufacturer.
But as I pointed out in my earlier contribution, there's a certain fear factor which has its roots in the thermal instability of AGM batteries, when being operated in very hot conditions, such as under the bonnet.
It's a reputation thing.
If the battery capacity goes away slowly yet prematurely, then the battery must have been of bad quality.
But if it dies at a later stage, in a spectacular and sudden way, then the charger manufacturer cops the blame.
cheers, Peter
FollowupID:
750690